Discussion Forum : Redox Reactions
Question -


H2S acts only as a reducing agent while SO2 can act both as a reducing and oxidizing agent because
 

Options:
A .   S in H2S has - 2 oxidation state
B .   S in SO2 has oxidation state + 4
C .   Hydrogen in H2S more +ve than oxygen
D .   Oxygen is more - ve in SO2
Answer: Option A
:
A and B

In H2S, Sulphur atom exhibits (-2) oxidation state, which is the least for the pnictogen.
As for its highest oxidation state - Sulphur exhibits (+6) in H2SO4.
In SO2, sulphur exhibits a (+4) oxidation state, which is in between the extremes.
Hence SO2 shows both oxidising and reducing properties.



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