Discussion Forum : Nomenclature Of Organic Compounds
Question -


The IUPAC name of the following compound is?


CH3−CH2−CH2−C|HCH3−CH2−CH3|CH−CH3

Options:
A .   2,4-Dimethylheptane
B .   4,6-Dimethylheptane
C .   2,4-Methylheptane
D .   2,3-Ethylheptane
Answer: Option A
:
A

Our first step should be to choose the longest chain from the given alkane.
Although there are 9 carbon atoms in total, the longest chain contains only 7 carbon atoms.


The IUPAC Name Of The Following Compound Is?CH3−CH2−CH2â...
Primary suffix = ane


Word root = hept 


If we number the chain, as shown above, the two methyl substituents are at C4 and C6


Now, let's look at another case.
The IUPAC Name Of The Following Compound Is?CH3−CH2−CH2â...
Now we have substituents at C2 and C4. In both cases, there are exactly two substituents.
We choose the numbering direction that gives the lowest set of locants.


Hence, secondary prefix = 2,4-dimethyl (since there are two methyl groups-one each at C2 and C4


Hence, the IUPAC name is 2,4-Dimethylheptane


 



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