Discussion Forum : Periodic Classification Of Elements
Question - The electron affinity values for the halogens show the following trend:
Options:
A .  F < Cl > Br > I
B .  F < Cl < Br < I
C .  F > Cl > Br > I
D .  F < Cl > Br < I
Answer: Option A
:
A
In a group of non-metals, electrongain enthalpy of the 2nd element is maximum. Among halogens, chlorine has the highest election affinity.
We would expect fluorine would have the highest electron affinity because of being a halogen and very small size, but its so small that it leads to interelectronic repulsions and the overall energy released when an electron is added is reduced.

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